David Mitzi
Thomas Lord Department of Mechanical Engineering and Materials Science
Simon Family Distinguished Professor
Research Themes
Energy Systems & Materials
Research Interests
Making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market.
Bio
David Mitzi received his B.S. in Electrical Engineering and Engineering Physics from Princeton University in 1985 and his Ph.D. in Applied Physics from Stanford University in 1990. Prior to joining the faculty at Duke in 2014, Dr. Mitzi spent 23 years at IBM’s T.J. Watson Research Center, where his focus was on the search for and application of new electronic materials, including organic-inorganic perovskites and inorganic materials for photovoltaic, LED, transistor and memory applications. For his final five years at IBM, he served as manager for the Photovoltaic Science and Technology Department, where he initiated and managed a multi-company program to develop a low-cost, high-throughput approach to deposit thin-film chalcogenide-based absorber layers for high-efficiency solar cells. Dr. Mitzi’s current research interests involve making emerging photovoltaic materials more effective, cost-efficient and competitive for the energy market. He holds a number of patents, and has authored or coauthored more than 200 papers and book chapters.
Education
- B.S. Princeton University, 1985
- Ph.D. Stanford University, 1990
Positions
- Simon Family Distinguished Professor
- Professor in the Thomas Lord Department of Mechanical Engineering and Materials Science
- Professor of Chemistry
Awards, Honors, and Distinctions
- Clarivate Analytics Highly Cited Researcher . Clarivate Analytics. 2023
- Clarivate Analytics Highly Cited Researcher . Clarivate Analytics. 2022
- Clarivate Analytics Highly Cited Researcher . Clarivate Analytics. 2021
- Clarivate Analytics Highly Cited Researcher . Clarivate Analytics. 2020
- ACS Award in the Chemistry of Materials. American Chemical Society. 2020
- Clarivate Analytics Highly Cited Researcher. Clarivate Analytics. 2019
- MRS Fellow. Materials Research Society. 2018
- Clarivate Analytics Highly Cited Researcher. Clarivate Analytics. 2018
Courses Taught
- MSEG 591: Independent Study
- ME 592: Research Independent Study in Mechanical Engineering or Material Science
- ME 591: Research Independent Study in Mechanical Engineering or Material Science
- ME 562: Materials Synthesis and Processing
- ME 555: Advanced Topics in Mechanical Engineering
- ME 516: Thin-Film Photovoltaic Technology
- ME 492: Special Projects in Mechanical Engineering
- ME 491: Special Projects in Mechanical Engineering
- EGR 393: Research Projects in Engineering
- ECE 391: Projects in Electrical and Computer Engineering
Publications
- Haque MA, Grieder A, Harvey SP, Brunecky R, Ye JY, Addison B, et al. Remote chirality transfer in low-dimensional hybrid metal halide semiconductors. Nature chemistry. 2024 Oct;
- Singh A, Dayton D, Ladd DM, Reuveni G, Paluch P, Montagne L, et al. Local Structure in Crystalline, Glass and Melt States of a Hybrid Metal Halide Perovskite. Journal of the American Chemical Society. 2024 Sep;146(37):25656–68.
- Wang S, Zhang Y, Halasyamani PS, Mitzi DB. Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response. Inorganic chemistry. 2024 Sep;63(35):16121–7.
- Xie Y, Koknat G, Weadock NJ, Wang X, Song R, Toney MF, et al. Hydrogen Bonding Analysis of Structural Transition-Induced Symmetry Breaking and Spin Splitting in a Hybrid Perovskite Employing a Synergistic Diffraction-DFT Approach. Journal of the American Chemical Society. 2024 Aug;146(32):22509–21.
- Xie Y, Hewa-Walpitage H, Morgenstein J, Blum V, Vardeny ZV, Mitzi DB. Homochiral and Heterochiral Cation Mixing in 2D Perovskites for Enhanced Structural Asymmetry and Spin Splitting. ACS Materials Letters. 2024 Jul 1;6(7):3161–7.
- Yan L, Xie Y, Mitzi DB, Sercel PC, Phillips AJ, Blackburn JL, et al. Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth-Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation. Advanced Optical Materials. 2024 May 6;12(13).
- Singh A, Xie Y, Adams C, Bobay BG, Mitzi DB. Controlling glass forming kinetics in 2D perovskites using organic cation isomers. Chem Sci. 2024 May 1;15(17):6432–44.
- Almora O, Cabrera CI, Erten-Ela S, Forberich K, Fukuda K, Guo F, et al. Device Performance of Emerging Photovoltaic Materials (Version 4). Advanced Energy Materials. 2024 Jan 26;14(4).
- Wang T, McWhorter TM, McKeown Wessler GC, Yao Y, Song R, Mitzi DB, et al. Exploration, Prediction, and Experimental Verification of Structure and Optoelectronic Properties in I
2 -Eu-IV-X4 (I = Li, Cu, Ag; IV = Si, Ge, Sn; X = S, Se) Chalcogenide Semiconductors. Chemistry of Materials. 2024 Jan 9;36(1):340–57. - Maughan AE, Koknat G, Sercel PC, Jana MK, Brunecky R, Mitzi DB, et al. Impact of Chiral Symmetry Breaking on Spin-Texture and Lone Pair Expression in Chiral Crystals of Hybrid Antimony and Bismuth Halides. Chemistry of Materials. 2023 Nov 14;35(21):9086–101.
- Luebbering H, Shafiee A, Teymur B, Kim Y, Mitzi DB, Ghadiri E. Ultrafast microscopy and image segmentation of spatially heterogeneous excited state and trap passivation in Cu
2 BaSnSSe3 . Cell Reports Physical Science. 2023 Oct 18;4(10). - Crace EJ, Singh A, Haley S, Claes B, Mitzi DB. Meltable Hybrid Antimony and Bismuth Iodide One-Dimensional Perovskites. Inorganic chemistry. 2023 Oct;62(39):16161–9.
- Xie Y, Morgenstein J, Bobay BG, Song R, Caturello NAMS, Sercel PC, et al. Chiral Cation Doping for Modulating Structural Symmetry of 2D Perovskites. J Am Chem Soc. 2023 Aug 16;145(32):17831–44.
- Singh A, Kim Y, Henry R, Ade H, Mitzi DB. Study of Glass Formation and Crystallization Kinetics in a 2D Metal Halide Perovskite Using Ultrafast Calorimetry. Journal of the American Chemical Society. 2023 Aug;145(33):18623–33.
- Song R, Liu C, Kanai Y, Mitzi DB, Blum V. Structure and electronic tunability of acene alkylamine based layered hybrid organic-inorganic perovskites from first principles. Physical Review Materials. 2023 Aug 1;7(8).
- Kim Y, Hempel H, Harvey SP, Rivera NA, Unold T, Mitzi DB. Alkali element (Li, Na, K, and Rb) doping of Cu
2 BaGe1−x Snx Se4 films. Journal of Materials Chemistry A. 2023 Jun 7;11(28):15336–46. - Singh A, Crace E, Xie Y, Mitzi DB. A two-dimensional lead-free hybrid perovskite semiconductor with reduced melting temperature. Chemical communications (Cambridge, England). 2023 Jun;59(53):8302–5.
- Seyitliyev D, Qin X, Jana MK, Janke SM, Zhong X, You W, et al. Coherent Phonon-Induced Modulation of Charge Transfer in 2D Hybrid Perovskites. Advanced Functional Materials. 2023 May 17;33(21).
- Kim Y, Hempel H, Unold T, Mitzi DB. Ag Alloying in Cu
2−y Agy Ba(Ge,Sn)Se4 Films and Photovoltaic Devices. Solar RRL. 2023 Apr 1;7(7). - Chang ET, Koknat G, McKeown Wessler GC, Yao Y, Blum V, Mitzi DB. Phase Stability, Band Gap Tuning, and Rashba Splitting in Selenium-Alloyed Bournonite: CuPbSb(S
1−x Sex )3 . Chemistry of Materials. 2023 Jan 24;35(2):595–608. - Almora O, Baran D, Bazan GC, Cabrera CI, Erten-Ela S, Forberich K, et al. Device Performance of Emerging Photovoltaic Materials (Version 3). Advanced Energy Materials. 2023 Jan 6;13(1).
- Teymur B, Kim Y, Huang J, Sun K, Hao X, Mitzi DB. Top Stack Optimization for Cu
2 BaSn(S, Se)4 Photovoltaic Cell Leads to Improved Device Power Conversion Efficiency beyond 6%. Advanced Energy Materials. 2022 Oct 27;12(40). - Mitzi DB, Kim Y. Spiers Memorial Lecture: Next generation chalcogenide-based absorbers for thin-film solar cells. Faraday discussions. 2022 Oct;239(0):9–37.
- Andreasen JW, Breternitz J, Bär M, Dale PJ, Dimitrievska M, Fermin DJ, et al. Bulk and surface characterisation techniques of solar absorbers: general discussion. Faraday discussions. 2022 Oct;239(0):180–201.
- Andreasen JW, Bowers JW, Breternitz J, Dale PJ, Dimitrievska M, Fermin DJ, et al. Indium-free CIGS analogues: general discussion. Faraday discussions. 2022 Oct;239(0):85–111.
- Andreasen JW, Arca E, Bowers JW, Bär M, Breternitz J, Dale PJ, et al. Novel chalcogenides, pnictides and defect-tolerant semiconductors: general discussion. Faraday discussions. 2022 Oct;239(0):287–316.
- Teymur B, Choubrac L, Hempel H, Gunawan O, Unold T, Mitzi DB. Influence of Copper Composition on Cu
2 BaSn(S,Se)4 Solution-Deposited Films and Photovoltaic Devices with over 5% Efficiency. ACS Applied Energy Materials. 2022 Sep 26;5(9):10645–56. - Singh A, Mitzi DB. Crystallization Kinetics in a Glass-Forming Hybrid Metal Halide Perovskite. ACS Materials Letters. 2022 Sep 5;4(9):1840–7.
- Xie Y, Song R, Singh A, Jana MK, Blum V, Mitzi DB. Kinetically Controlled Structural Transitions in Layered Halide-Based Perovskites: An Approach to Modulate Spin Splitting. Journal of the American Chemical Society. 2022 Aug;144(33):15223–35.
- Jana MK, Xie Y, Mitzi DB. Impact of Structural Distortions on the Optoelectronic and Spin-Related Properties of Two-Dimensional Hybrid Perovskites. In: Materials and Energy. 2022. p. 1–61.
- McKeown Wessler GC, Wang T, Blum V, Mitzi DB. Cubic Crystal Structure Formation and Optical Properties within the Ag-BII-MIV-X (BII = Sr, Pb; MIV = Si, Ge, Sn; X = S, Se) Family of Semiconductors. Inorganic chemistry. 2022 Feb;61(6):2929–44.
- Yang C, Atwater HA, Baldo MA, Baran D, Barile CJ, Barr MC, et al. Consensus statement: Standardized reporting of power-producing luminescent solar concentrator performance. Joule. 2022 Jan;6(1):8–15.
- Almora O, Baran D, Bazan GC, Berger C, Cabrera CI, Catchpole KR, et al. Device Performance of Emerging Photovoltaic Materials (Version 2). Advanced Energy Materials. 2021 Dec 1;11(48).
- Kim Y, Hempel H, Levcenco S, Euvrard J, Bergmann E, Gunawan O, et al. Optoelectronic property comparison for isostructural Cu
2 BaGeSe4 and Cu2 BaSnS4 solar absorbers. Journal of Materials Chemistry A. 2021 Nov 7;9(41):23619–30. - Yan L, Jana MK, Sercel PC, Mitzi DB, You W. Alkyl-Aryl Cation Mixing in Chiral 2D Perovskites. Journal of the American Chemical Society. 2021 Nov;143(43):18114–20.
- Levcenko S, Teymur B, Mitzi DB, Unold T. Photoluminescence study of solution-deposited Cu
2 BaSnS4 thin films. APL Materials. 2021 Nov 1;9(11). - Kim Y, Mitzi DB. Growth and Photovoltaic Device Application of Cu
2 BaGe1- x Snx Se4 Films Prepared by Selenization of Sequentially Deposited Precursors. ACS Applied Energy Materials. 2021 Oct 25;4(10):11528–36. - McKeown Wessler GC, Wang T, Sun J-P, Liao Y, Fischer MC, Blum V, et al. Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS4. Inorganic chemistry. 2021 Aug;60(16):12206–17.
- Jana MK, Song R, Xie Y, Zhao R, Sercel PC, Blum V, et al. Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites. Nature communications. 2021 Aug;12(1):4982.
- Euvrard J, Yan Y, Mitzi DB. Electrical doping in halide perovskites. Nature Reviews Materials. 2021 Jun 1;6(6):531–49.
- Euvrard J, Gunawan O, Zhong X, Harvey SP, Kahn A, Mitzi DB. P-Type molecular doping by charge transfer in halide perovskite. Materials Advances. 2021 May 7;2(9):2956–65.
- Li C, Ma H, Li T, Dai J, Rasel MAJ, Mattoni A, et al. Remarkably Weak Anisotropy in Thermal Conductivity of Two-Dimensional Hybrid Perovskite Butylammonium Lead Iodide Crystals. Nano letters. 2021 May;21(9):3708–14.
- Jana M, Song R, Xie Y, Zhao R, Sercel P, Blum V, et al. Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites. Research Square Platform LLC. 2021.
- Abdelsamie M, Li T, Babbe F, Xu J, Han Q, Blum V, et al. Mechanism of Additive-Assisted Room-Temperature Processing of Metal Halide Perovskite Thin Films. ACS applied materials & interfaces. 2021 Mar;13(11):13212–25.
- Almora O, Baran D, Bazan GC, Berger C, Cabrera CI, Catchpole KR, et al. Device Performance of Emerging Photovoltaic Materials (Version 1). Advanced Energy Materials. 2021 Mar 1;11(11).
- Teymur B, Levcenco S, Hempel H, Bergmann E, Márquez JA, Choubrac L, et al. Optoelectronic and material properties of solution-processed Earth-abundant Cu
2 BaSn(S, Se)4 films for solar cell applications. Nano Energy. 2021 Feb 1;80. - Song J, Teymur B, Zhou Y, Ngaboyamahina E, Mitzi DB. Porous Cu
2 BaSn(S,Se)4 Film as a Photocathode Using Non-Toxic Solvent and a Ball-Milling Approach. ACS Applied Energy Materials. 2021 Jan 25;4(1):81–7. - Singh A, Jana MK, Mitzi DB. Reversible Crystal-Glass Transition in a Metal Halide Perovskite. Advanced materials (Deerfield Beach, Fla). 2021 Jan;33(3):e2005868.
- Takeoka Y, Mitzi DB. Halide Perovskite Materials, Structural Dimensionality, and Synthesis. In: Perovskite Photovoltaics and Optoelectronics: From Fundamentals to Advanced Applications. 2021. p. 61–79.
- Li T, Dunlap-Shohl WA, Mitzi DB. Bifacial perovskite solar cells via a rapid lamination process. ACS Applied Energy Materials. 2020 Oct 26;3(10):9493–7.
- Jana MK, Song R, Liu H, Khanal DR, Janke SM, Zhao R, et al. Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit coupling. Nature communications. 2020 Sep;11(1):4699.
- Jiang T, Bai Y, Zhang P, Han Q, Mitzi DB, Therien MJ. Electronic structure and photophysics of a supermolecular iron complex having a long MLCT-state lifetime and panchromatic absorption. Proceedings of the National Academy of Sciences of the United States of America. 2020 Aug;117(34):20430–7.
- Sun JP, McKeown Wessler GC, Wang T, Zhu T, Blum V, Mitzi DB. Erratum: Structural tolerance factor approach to defect-resistant I
2 ‑II-IV‑X4 semiconductor design (Chemistry of Materials (2020) 32:4 (1636-1649) DOI: 10.1021/acs.chemmater.9b05107). Chemistry of Materials. 2020 Jul 14;32(13):5925–6. - Lu H, Xiao C, Song R, Li T, Maughan AE, Levin A, et al. Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport. Journal of the American Chemical Society. 2020 Jul;142(30):13030–40.
- Márquez JA, Sun JP, Stange H, Ali H, Choubrac L, Schäfer S, et al. High-temperature decomposition of Cu
2 BaSnS4 with Sn loss reveals newly identified compound Cu2 Ba3 Sn2 S8 . Journal of Materials Chemistry A. 2020 Jun 14;8(22):11346–53. - Gunawan O, Pae SR, Bishop DM, Shin B, Virgus Y, Mitzi DB. Carrier-Resolved Photo-Hall Effect: Unlocking a 140-year-old secret in Hall effect. In: Conference Record of the IEEE Photovoltaic Specialists Conference. 2020. p. 2126–9.
- Ye F, Wu H, Qin M, Yang S, Niu G, Lu X, et al. High-Quality MAPbBr3 Cuboid Film with Promising Optoelectronic Properties Prepared by a Hot Methylamine Precursor Approach. ACS applied materials & interfaces. 2020 May;12(21):24498–504.
- Sun JP, McKeown Wessler GC, Wang T, Zhu T, Blum V, Mitzi DB. Structural Tolerance Factor Approach to Defect-Resistant I
2 -II-IV-X4 Semiconductor Design. Chemistry of Materials. 2020 Feb 25;32(4):1636–49. - Euvrard J, Wang X, Li T, Yan Y, Mitzi DB. Is Cs
2 TiBr6 a promising Pb-free perovskite for solar energy applications? Journal of Materials Chemistry A. 2020 Feb 21;8(7):4049–54. - Li T, Chen X, Wang X, Lu H, Yan Y, Beard MC, et al. Origin of Broad-Band Emission and Impact of Structural Dimensionality in Tin-Alloyed Ruddlesden−Popper Hybrid Lead Iodide Perovskites. ACS Energy Letters. 2020 Feb 14;5(2):347–52.
- Todorov T, Hillhouse HW, Aazou S, Sekkat Z, Vigil-Galán O, Deshmukh SD, et al. Solution-based synthesis of kesterite thin film semiconductors. JPhys Energy. 2020 Jan 1;2(1).
- Euvrard J, Gunawan O, Mitzi DB. Impact of PbI
2 Passivation and Grain Size Engineering in CH3 NH3 PbI3 Solar Absorbers as Revealed by Carrier-Resolved Photo-Hall Technique. Advanced Energy Materials. 2019 Dec 1;9(47). - Gunawan O, Pae SR, Bishop DM, Virgus Y, Noh JH, Jeon NJ, et al. Carrier-resolved photo-Hall effect. Nature. 2019 Nov;575(7781):151–5.
- Jana MK, Liu C, Lidin S, Dirkes DJ, You W, Blum V, et al. Resolving rotational stacking disorder and electronic level alignment in a 2d oligothiophene-based lead iodide perovskite. Chemistry of Materials. 2019 Oct 22;31(20):8523–32.
- Dunlap-Shohl WA, Barraza ET, Barrette A, Dovletgeldi S, Findik G, Dirkes DJ, et al. Tunable internal quantum well alignment in rationally designed oligomer-based perovskite films deposited by resonant infrared matrix-assisted pulsed laser evaporation. Materials Horizons. 2019 Oct 1;6(8):1707–16.
- Zhang B, Thampy S, Dunlap-Shohl WA, Xu W, Zheng Y, Cao F-Y, et al. Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells. Nanomaterials (Basel, Switzerland). 2019 Sep;9(9):E1311.
- Jana MK, Janke S, Dirkes D, Dovletgeldi S, Liu C, Qin X, et al. Direct-bandgap 2D silver-bismuth iodide double perovskite: Structure-directing influence of an oligothiophene spacer cation. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2019.
- Dunlap-Shohl WA, Li T, Mitzi DB. Interfacial Effects during Rapid Lamination within MAPbI
3 Thin Films and Solar Cells. ACS Applied Energy Materials. 2019 Jul 22;2(7):5083–93. - Li T, Zeidell AM, Findik G, Dunlap-Shohl WA, Euvrard J, Gundogdu K, et al. Phase-Pure Hybrid Layered Lead Iodide Perovskite Films Based on a Two-Step Melt-Processing Approach. Chemistry of Materials. 2019 Jun 11;31(11):4267–74.
- Sun JP, Márquez JA, Stange H, Mainz R, Mitzi DB. Phase and film formation pathway for vacuum-deposited C u2BaSn(S,Se)4 absorber layers. Physical Review Materials. 2019 May 15;3(5).
- Jana MK, Janke SM, Dirkes DJ, Dovletgeldi S, Liu C, Qin X, et al. Direct-Bandgap 2D Silver-Bismuth Iodide Double Perovskite: The Structure-Directing Influence of an Oligothiophene Spacer Cation. Journal of the American Chemical Society. 2019 May;141(19):7955–64.
- Mitzi DB. Introduction: Perovskites. Chemical reviews. 2019 Mar;119(5):3033–5.
- Dunlap-Shohl WA, Zhou Y, Padture NP, Mitzi DB. Synthetic Approaches for Halide Perovskite Thin Films. Chemical reviews. 2019 Mar;119(5):3193–295.
- Ding J, Han Q, Ge QQ, Xue DJ, Ma JY, Zhao BY, et al. Fully Air-Bladed High-Efficiency Perovskite Photovoltaics. Joule. 2019 Feb 20;3(2):402–16.
- Zhu LL, Huang YE, Lin YP, Huang XY, Liu HQ, Mitzi DB, et al. Stereochemically active lead chloride enantiomers mediated by homochiral organic cation. Polyhedron. 2019 Jan 15;158:445–8.
- Khazaee M, Sardashti K, Chung CC, Sun JP, Zhou H, Bergmann E, et al. Dual-source evaporation of silver bismuth iodide films for planar junction solar cells. Journal of Materials Chemistry A. 2019 Jan 1;7(5):2095–105.
- Li T, Dunlap-Shohl WA, Reinheimer EW, Le Magueres P, Mitzi DB. Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching. Chemical science. 2019 Jan;10(4):1168–75.
- Dunlap-Shohl WA, Hill IG, Yan Y, Mitzi DB. Photovoltaic Effect in Indium(I) Iodide Thin Films. Chemistry of Materials. 2018 Nov 27;30(22):8226–32.
- Ghadiri E, Shin D, Shafiee A, Warren WS, Mitzi DB. Grain-Resolved Ultrafast Photophysics in Cu2BaSnS4- xSe x Semiconductors Using Pump-Probe Diffuse Reflectance Spectroscopy and Microscopy. ACS applied materials & interfaces. 2018 Nov;10(46):39615–23.
- Han Q, Ding J, Bai Y, Li T, Ma JY, Chen YX, et al. Carrier Dynamics Engineering for High-Performance Electron-Transport-Layer-free Perovskite Photovoltaics. Chem. 2018 Oct 11;4(10):2405–17.
- Liu C, Huhn W, Du K-Z, Vazquez-Mayagoitia A, Dirkes D, You W, et al. Tunable Semiconductors: Control over Carrier States and Excitations in Layered Hybrid Organic-Inorganic Perovskites. Physical review letters. 2018 Oct;121(14):146401.
- Wessler GC, Zhu T, Sun JP, Harrell A, Huhn WP, Blum V, et al. Band Gap Tailoring and Structure-Composition Relationship within the Alloyed Semiconductor Cu
2 BaGe1- x Snx Se4 . Chemistry of Materials. 2018 Sep 25;30(18):6566–74. - Teymur B, Zhou Y, Ngaboyamahina E, Glass JT, Mitzi DB. Solution-Processed Earth-Abundant Cu
2 BaSn(S,Se)4 Solar Absorber Using a Low-Toxicity Solvent. Chemistry of Materials. 2018 Sep 11;30(17):6116–23. - Jiang T, Bai Y, Han Q, Mitzi D, Therien M. How to turn iron into ruthenium. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2018.
- Li T, Wang X, Yan Y, Mitzi DB. Phase Stability and Electronic Structure of Prospective Sb-Based Mixed Sulfide and Iodide 3D Perovskite (CH3NH3)SbSI2. The journal of physical chemistry letters. 2018 Jul;9(14):3829–33.
- Khazaee M, Sardashti K, Sun JP, Zhou H, Clegg C, Hill IG, et al. A Versatile Thin-Film Deposition Method for Multidimensional Semiconducting Bismuth Halides. Chemistry of Materials. 2018 May 22;30(10):3538–44.
- Mitzi D. Halide perovskites beyond CH3NH3PbI3: Structural diversity and opportunities for semiconductor design. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2018.
- Dunlap-Shohl WA, Barraza ET, Barrette A, Gundogdu K, Stiff-Roberts AD, Mitzi DB. MAPbI
3 Solar Cells with Absorber Deposited by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. ACS Energy Letters. 2018 Feb 9;3(2):270–5. - Barraza ET, Dunlap-Shohl WA, Mitzi DB, Stiff-Roberts AD. Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation. Journal of Electronic Materials. 2018 Feb 1;47(2):917–26.
- Zhou Y, Shin D, Ngaboyamahina E, Han Q, Parker CB, Mitzi DB, et al. Efficient and Stable Pt/TiO
2 /CdS/Cu2 BaSn(S,Se)4 Photocathode for Water Electrolysis Applications. ACS Energy Letters. 2018 Jan 12;3(1):177–83. - Dunlap-Shohl WA, Daunis TB, Wang X, Wang J, Zhang B, Barrera D, et al. Room-temperature fabrication of a delafossite CuCrO
2 hole transport layer for perovskite solar cells. Journal of Materials Chemistry A. 2018 Jan 1;6(2):469–77. - Stiff-Roberts AD, Mitzi DB, Barraza ET, Dunlap-Shohl WA. Resonant infrared matrix-assisted pulsed laser evaporation of hybrid perovskites. In: Optics InfoBase Conference Papers. 2018.
- Liu J, Han Q, Bai Y, Du KZ, Li T, Ji D, et al. Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes. Energy and Environmental Science. 2017 Nov 1;10(11):2365–71.
- Du KZ, Wang X, Han Q, Yan Y, Mitzi DB. Heterovalent B-Site Co-Alloying Approach for Halide Perovskite Bandgap Engineering. ACS Energy Letters. 2017 Oct 13;2(10):2486–90.
- Zhu T, Huhn WP, Wessler GC, Shin D, Saparov B, Mitzi DB, et al. I
2 -II-IV-VI4 (I = Cu, Ag; II = Sr, Ba; IV = Ge, Sn; VI = S, Se): Chalcogenides for Thin-Film Photovoltaics. Chemistry of Materials. 2017 Sep 26;29(18):7868–79. - Xiao Z, Du K, Meng W, Mitzi DB, Yan Y. Chemical Origin of the Stability Difference between Copper(I)‐ and Silver(I)‐Based Halide Double Perovskites. Angewandte Chemie. 2017 Sep 25;129(40):12275–9.
- Xiao Z, Du K-Z, Meng W, Mitzi DB, Yan Y. Chemical Origin of the Stability Difference between Copper(I)- and Silver(I)-Based Halide Double Perovskites. Angewandte Chemie (International ed in English). 2017 Sep;56(40):12107–11.
- Li T, Dunlap-Shohl WA, Han Q, Mitzi DB. Melt Processing of Hybrid Organic-Inorganic Lead Iodide Layered Perovskites. Chemistry of Materials. 2017 Aug 8;29(15):6200–4.
- Du K-Z, Tu Q, Zhang X, Han Q, Liu J, Zauscher S, et al. Two-Dimensional Lead(II) Halide-Based Hybrid Perovskites Templated by Acene Alkylamines: Crystal Structures, Optical Properties, and Piezoelectricity. Inorganic chemistry. 2017 Aug;56(15):9291–302.
- Du K, Meng W, Wang X, Yan Y, Mitzi DB. Bandgap Engineering of Lead‐Free Double Perovskite Cs2AgBiBr6 through Trivalent Metal Alloying. Angewandte Chemie. 2017 Jul 3;129(28):8270–4.
- Xiao Z, Du K-Z, Meng W, Wang J, Mitzi DB, Yan Y. Correction to "Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study". Journal of the American Chemical Society. 2017 Jul;139(27):9409.
- Du K-Z, Meng W, Wang X, Yan Y, Mitzi DB. Bandgap Engineering of Lead-Free Double Perovskite Cs2 AgBiBr6 through Trivalent Metal Alloying. Angewandte Chemie (International ed in English). 2017 Jul;56(28):8158–62.
- Meng W, Wang X, Xiao Z, Wang J, Mitzi DB, Yan Y. Parity-Forbidden Transitions and Their Impact on the Optical Absorption Properties of Lead-Free Metal Halide Perovskites and Double Perovskites. The journal of physical chemistry letters. 2017 Jul;8(13):2999–3007.
- Shin D, Saparov B, Mitzi DB. Defect Engineering in Multinary Earth-Abundant Chalcogenide Photovoltaic Materials. Advanced Energy Materials. 2017 Jun 7;7(11).
- Shin D, Zhu T, Huang X, Gunawan O, Blum V, Mitzi DB. Earth-Abundant Chalcogenide Photovoltaic Devices with over 5% Efficiency Based on a Cu2 BaSn(S,Se)4 Absorber. Advanced materials (Deerfield Beach, Fla). 2017 Jun;29(24).
- Xiao Z, Du K-Z, Meng W, Wang J, Mitzi DB, Yan Y. Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study. Journal of the American Chemical Society. 2017 May;139(17):6054–7.
- Wallace SK, Mitzi DB, Walsh A. The steady rise of kesterite solar cells. ACS Energy Letters. 2017 Apr 14;2(4):776–9.
- Keenan E, Hu J, Zhi J, Mitzi D, You W. Diffusion of cations in 2D/3D perovskite films made by melt infiltration. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2017.
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- Xiao Z, Meng W, Mitzi DB, Yan Y. Crystal Structure of AgBi2I7 Thin Films. The journal of physical chemistry letters. 2016 Oct;7(19):3903–7.
- Chagarov E, Sardashti K, Haight R, Mitzi DB, Kummel AC. Density-functional theory computer simulations of CZTS
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2 Sn(S,Se)4 : Earth-abundant chalcogenides for thin-film photovoltaics. Chemistry of Materials. 2016 Jul 12;28(13):4771–80. - Ke W, Xiao C, Wang C, Saparov B, Duan H-S, Zhao D, et al. Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells. Advanced materials (Deerfield Beach, Fla). 2016 Jul;28(26):5214–21.
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- Hong F, Saparov B, Meng W, Xiao Z, Mitzi DB, Yan Y. Viability of Lead-Free Perovskites with Mixed Chalcogen and Halogen Anions for Photovoltaic Applications. Journal of Physical Chemistry C. 2016 Mar 31;120(12):6435–41.
- Meng W, Saparov B, Hong F, Wang J, Mitzi DB, Yan Y. Alloying and Defect Control within Chalcogenide Perovskites for Optimized Photovoltaic Application. Chemistry of Materials. 2016 Feb 9;28(3):821–9.
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2 ZnSn(Sx Se1-x )4 Solar Cells: Insights from Physical and Electrical Characterization of Devices and Exfoliated Films. Advanced Energy Materials. 2016 Feb 4;6(3). - Gunawan O, Gokmen T, Mitzi DB. High intensity and integrated Suns-Voc characterization of high performance kesterite solar cells. In: 2015 IEEE 42nd Photovoltaic Specialist Conference, PVSC 2015. 2015.
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- Abou-Ras D, Edoff M, Minemoto T, Mitzi D, Romeo A. Preface. Thin Solid Films. 2015 May 1;582:1.
- Sardashti K, Haight R, Gokmen T, Wang W, Chang LY, Mitzi DB, et al. Impact of nanoscale elemental distribution in high-performance kesterite solar cells. Advanced Energy Materials. 2015 May 1;5(10).
- Gunawan O, Gokmen T, Mitzi DB. Device Characteristics of Hydrazine-Processed CZTSSe. In: Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells. 2015. p. 387–411.
- Bishop DM, McCandless BE, Haight R, Mitzi DB, Birkmire RW. Fabrication and electronic properties of CZTSe single crystals. IEEE Journal of Photovoltaics. 2015 Jan 1;5(1):390–4.
- Gershon T, Shin B, Bojarczuk N, Hopstaken M, Mitzi DB, Guha S. The role of sodium as a surfactant and suppressor of non-radiative recombination at internal surfaces in Cu
2 ZnSnS4 . Advanced Energy Materials. 2015 Jan 1;5(2). - Park HH, Jayaraman A, Heasley R, Yang C, Hartle L, Mankad R, et al. Atomic layer deposition of Al-incorporated Zn(O,S) thin films with tunable electrical properties. Applied Physics Letters. 2014 Nov 17;105(20).
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2 ZnSn(SeS)4 solar cell via hybrid buffer layer. 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014. 2014 Oct 15;30–2. - Patel P, Mitzi D. Perovskites in the spotlight. MRS Bulletin. 2014 Sep 10;39(9):768–9.
- Gokmen T, Gunawan O, Mitzi DB. Semi-empirical device model for Cu
2 ZnSn(S,Se)4 solar cells. Applied Physics Letters. 2014 Jul 21;105(3). - Wang W, Winkler MT, Gunawan O, Gokmen T, Todorov TK, Zhu Y, et al. Device characteristics of CZTSSe thin-film solar cells with 12.6% efficiency. Advanced Energy Materials. 2014 May 13;4(7).
- Winkler MT, Wang W, Gunawan O, Hovel HJ, Todorov TK, Mitzi DB. Optical designs that improve the efficiency of Cu
2 ZnSn(S,Se)4 solar cells. Energy and Environmental Science. 2014 Mar 1;7(3):1029–36. - Haight R, Shao X, Wang W, Mitzi DB. Electronic and elemental properties of the Cu
2 ZnSn(S,Se)4 surface and grain boundaries. Applied Physics Letters. 2014 Jan 20;104(3). - Gunawan O, Gokmen T, Mitzi DB. Suns- V
OC characteristics of high performance kesterite solar cells. Journal of Applied Physics. 2014 Jan 1;116(8). - Todorov T, Sugimoto H, Gunawan O, Gokmen T, Mitzi DB. High-efficiency devices with pure solution-processed Cu
2 ZnSn(S,Se)4 Absorbers. IEEE Journal of Photovoltaics. 2014 Jan 1;4(1):483–5. - Haight R, Barkhouse A, Wang W, Luo Y, Shao X, Mitzi DB, et al. CdS and Cd-free buffer layers on solution phase grown Cu
2 ZnSn(Sx Se1- x )4 :Band alignments and electronic structure determined with femtosecond ultraviolet photoelectron spectroscopy. Materials Research Society Symposium Proceedings. 2014 Jan 1;1638. - Polizzotti A, Repins IL, Noufi R, Wei SH, Mitzi DB. The state and future prospects of kesterite photovoltaics. Energy and Environmental Science. 2013 Nov 1;6(11):3171–82.
- Gokmen T, Gunawan O, Mitzi DB. Minority carrier diffusion length extraction in Cu
2 ZnSn(Se,S)4 solar cells. Journal of Applied Physics. 2013 Sep 21;114(11). - Gokmen T, Gunawan O, Todorov TK, Mitzi DB. Band tailing and efficiency limitation in kesterite solar cells. Applied Physics Letters. 2013 Sep 2;103(10).
- Mitzi DB, Gunawan O, Todorov TK, Barkhouse DAR. Prospects and performance limitations for Cu-Zn-Sn-S-Se photovoltaic technology. Philosophical transactions Series A, Mathematical, physical, and engineering sciences. 2013 Aug;371(1996):20110432.
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- Todorov TK, Gunawan O, Gokmen T, Mitzi DB. Solution-processed Cu(In,Ga)(S,Se)
2 absorber yielding a 15.2% efficient solar cell. Progress in Photovoltaics: Research and Applications. 2013 Jan 1;21(1):82–7. - Todorov TK, Tang J, Bag S, Gunawan O, Gokmen T, Zhu Y, et al. Beyond 11% effi ciency: Characteristics of state-of-the-art Cu
2 ZnSn(S,Se)4 Solar Cells. Advanced Energy Materials. 2013 Jan 1;3(1):34–8. - Bag S, Gunawan O, Gokmen T, Zhu Y, Mitzi DB. Hydrazine-processed Ge-substituted CZTSe solar cells. Chemistry of Materials. 2012 Dec 11;24(23):4588–93.
- Miller DW, Warren CW, Gunawan O, Gokmen T, Mitzi DB, Cohen JD. Electronically active defects in the Cu
2 ZnSn(Se,S)4 alloys as revealed by transient photocapacitance spectroscopy. Applied Physics Letters. 2012 Oct 1;101(14). - Graetzel M, Janssen RAJ, Mitzi DB, Sargent EH. Materials interface engineering for solution-processed photovoltaics. Nature. 2012 Aug;488(7411):304–12.
- Gunawan O, Gokmen T, Warren CW, Cohen JD, Todorov TK, Barkhouse DAR, et al. Electronic properties of the Cu
2 ZnSn(Se,S)4 absorber layer in solar cells as revealed by admittance spectroscopy and related methods. Applied Physics Letters. 2012 Jun 18;100(25). - Barkhouse DAR, Haight R, Sakai N, Hiroi H, Sugimoto H, Mitzi DB. Cd-free buffer layer materials on Cu
2 ZnSn(Sx Se1-x )4 : Band alignments with ZnO, ZnS, and In2 S3 . Applied Physics Letters. 2012 May 7;100(19). - Bag S, Gunawan O, Gokmen T, Zhu Y, Todorov TK, Mitzi DB. Low band gap liquid-processed CZTSe solar cell with 10.1% efficiency. Energy and Environmental Science. 2012 May 1;5(5):7060–5.
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2 ZnSn(Se,S)4 solar cell. Progress in Photovoltaics: Research and Applications. 2012 Jan 1;20(1):6–11. - Shin B, Wang K, Gunawan O, Reuter KB, Chey SJ, Bojarczuk NA, et al. High efficiency Cu
2 ZnSn(Sx Se1-x )4 thin film solar cells by thermal co-evaporation. Conference Record of the IEEE Photovoltaic Specialists Conference. 2011 Dec 1;002510–4. - Li J, Mitzi DB, Shenoy VB. Structure and electronic properties of grain boundaries in earth-abundant photovoltaic absorber Cu2ZnSnSe4. ACS nano. 2011 Nov;5(11):8613–9.
- Cao Q, Gunawan O, Copel M, Reuter KB, Chey SJ, Deline VR, et al. Defects in Cu(In,Ga)Se
2 chalcopyrite semiconductors: A comparative study of material properties, defect states, and photovoltaic performance. Advanced Energy Materials. 2011 Oct 1;1(5):845–53. - Todorov T, Gunawan O, Chey SJ, De Monsabert TG, Prabhakar A, Mitzi DB. Progress towards marketable earth-abundant chalcogenide solar cells. Thin Solid Films. 2011 Aug 31;519(21):7378–81.
- Mitzi DB, Todorov TK, Gunawan O, Barkhouse AR, Bag S, Qiu X, et al. Slurry-based processing of high-performance CZTSSe photovoltaic absorber layers. In: ACS National Meeting Book of Abstracts. 2011.
- Haight R, Barkhouse A, Gunawan O, Shin B, Copel M, Hopstaken M, et al. Band alignment at the Cu
2 ZnSn (Sx Se1-x )4 /CdS interface. Applied Physics Letters. 2011 Jun 20;98(25). - Mitzi DB, Gunawan O, Todorov TK, Wang K, Guha S. The path towards a high-performance solution-processed kesterite solar cell. Solar Energy Materials and Solar Cells. 2011 Jun 1;95(6):1421–36.
- Wang K, Shin B, Reuter KB, Todorov T, Mitzi DB, Guha S. Structural and elemental characterization of high efficiency Cu
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- Gunawan O, Todorov TK, Mitzi DB. Loss mechanisms in hydrazine-processed Cu
2 ZnSn (Se,S)4 solar cells. Applied Physics Letters. 2010 Dec 6;97(23). - Yuan M, Mitzi DB, Gunawan O, Kellock AJ, Chey SJ, Deline VR. Antimony assisted low-temperature processing of CuIn
1 - X Gax Se2 - y Sy solar cells. Thin Solid Films. 2010 Nov 1;519(2):852–6. - Wang K, Gunawan O, Todorov T, Shin B, Chey SJ, Bojarczuk NA, et al. Thermally evaporated Cu
2 ZnSnS4 solar cells. Applied Physics Letters. 2010 Oct 4;97(14). - Hibberd CJ, Chassaing E, Liu W, Mitzi DB, Lincot D, Tiwari AN. Non-vacuum methods for formation of Cu(In, Ga)(Se, S)
2 thin film photovoltaic absorbers. Progress in Photovoltaics: Research and Applications. 2010 Sep 1;18(6):434–52. - Mitzi D. Plain-as-dirt solar cell may lower material costs. LASER FOCUS WORLD. 2010 May 1;46(5):9–9.
- Todorov TK, Reuter KB, Mitzi DB. High-efficiency solar cell with Earth-abundant liquid-processed absorber. Advanced materials (Deerfield Beach, Fla). 2010 May;22(20):E156–9.
- Liu W, Mitzi DB, Yuan M, Kellock AJ, Jay Chey S, Gunawan O. 12% Efficiency CuIn(Se,S)
2 photovoltaic device prepared using a hydrazine solution process. Chemistry of Materials. 2010 Feb 9;22(3):1010–4. - Yuan M, Mitzi DB, Liu W, Kellock AJ, Jay Chey S, Deline VR. Optimization of CIGS-based PV device through antimony doping. Chemistry of Materials. 2010 Jan 26;22(2):285–7.
- Todorov T, Mitzi DB. Direct liquid coating of chalcopyrite light-absorbing layers for photovoltaic devices. European Journal of Inorganic Chemistry. 2010 Jan 1;(1):17–28.
- Liu W, Mitzi DB, Chey SJ, Kellock A. CuIn(Se,S)
2 absorbers processed using a hydrazine-based solution approach. In: Materials Research Society Symposium Proceedings. 2009. p. 117–22. - Jay Chey S, Liu W, Yuan M, Mitzi DB. Characterization of indium tin oxide and al-doped zinc oxide thin films deposited by confocal RF magnetron sputter deposition. Conference Record of the IEEE Photovoltaic Specialists Conference. 2009 Dec 1;001149–53.
- Mitzi DB. Solution processing of chalcogenide semiconductors via dimensional reduction. Advanced Materials. 2009 Aug 21;21(31):3141–58.
- Yuan M, Mitzi DB. Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films. Dalton transactions (Cambridge, England : 2003). 2009 Aug;(31):6078–88.
- Mitzi DB. PHYS 485-Solution processing of CIGS absorber layers using a hydrazine-based approach. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2009 Mar 22;237.
- Mitzi DB, Yuan M, Liu W, Kellock AJ, Chey SJ, Gignac L, et al. Hydrazine-based deposition route for device-quality CIGS films. In: Thin Solid Films. 2009. p. 2158–62.
- Chey SJ, Wei L, Min Y, Mitzi DB. CHARACTERIZATION OF INDIUM TIN OXIDE AND AL-DOPED ZINC OXIDE THIN FILMS DEPOSITED BY CONFOCAL RF MAGNETRON SPUTTER DEPOSITION. In: 2009 34TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE, VOLS 1-3. IEEE; 2009. p. 29–33.
- Mitzi DB, Min Yuan, Wei Liu, Kellock A, Chey SJ, Schrott A, et al. Solution processing of CIGS absorber layers using a hydrazine-based approach. In: Conference Record of the IEEE Photovoltaic Specialists Conference. 2008.
- Mitzi DB, Yuan M, Liu W, Kellock AJ, Jay Chey S, Deline V, et al. A high-efficiency solution-deposited thin-film photovoltaic device. Advanced Materials. 2008 Oct 2;20(19):3657–62.
- Mitzi DB. Solution Processing of Inorganic Materials. Solution Processing of Inorganic Materials. 2008 May 14;1–497.
- Mitzi DB. Solution Processing of Chalcogenide Semiconductors via Dimensional Reduction. 2008 May 14;77–108.
- Tromp RM, Afzali A, Freitag M, Mitzi DB, Chen Z. Novel strategy for diameter-selective separation and functionalization of single-wall carbon nanotubes. Nano letters. 2008 Feb;8(2):469–72.
- Kanatzidis MG, Poeppelmeier KR, Bobev S, Guloy AM, Hwu SJ, Lachgar A, et al. Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences. Progress in Solid State Chemistry. 2008 Jan 1;36(1–2):1–133.
- Mitzi DB, Afzali A. Diels-alder adduct of pentacene and maleimide: Crystal growth and the influence of solvent molecules on structure and hydrogen bonding. Crystal Growth and Design. 2007 Apr 1;7(4):691–7.
- Mitzi DB. N4H9Cu7S4: a hydrazinium-based salt with a layered Cu7S4- framework. Inorganic chemistry. 2007 Feb;46(3):926–31.
- Mitzi DB. Synthesis, structure, and properties of organic-inorganic perovskites and related materials. 2007 Jan 1;48:1–121.
- Mitzi DB, Raoux S, Schrott AG, Copel M, Kellock A, Jordan-Sweet J. Solution-based processing of the phase-change material KSb
5 S8 . Chemistry of Materials. 2006 Dec 26;18(26):6278–82. - Mitzi DB, Copel M, Murray CE. High-mobility p-type transistor based on a spin-coated metal telluride semiconductor. Advanced Materials. 2006 Sep 18;18(18):2448–52.
- Milliron DJ, Mitzi DB. Solution processed metal chalcogenide thin films for flexible and large scale electronics. In: ACS National Meeting Book of Abstracts. 2006.
- Milliron DJ, Mitzi DB, Copel M, Murray CE. Solution-processed metal chalcogenide films for p-type transistors. Chemistry of Materials. 2006 Feb 7;18(3):581–90.
- Talapin DV, Mitzi DB, Shevchenko EV, Alivisatos AP, Murray CB. Novel inorganic materials for solution-processed electronics. In: Device Research Conference - Conference Digest, DRC. 2006. p. 285–6.
- Mitzi DB, Copel M, Murray CE, Kosbar LL, Afzali A. Thin-film transistors based on spin-coated chalcogenide semiconductor channels. Proceedings - Electrochemical Society. 2005 Dec 19;PV 2004-15:189–99.
- Mitzi DB, Milliron DJ, Copel M, Murray C, Kosbar L. High mobility solution-deposited chalcogenide films for flexible applications. In: 2005 IEEE VLSI-TSA - International Symposium on VLSI Technology - VLSI-TSA-TECH, Proceedings of Technical Papers. 2005. p. 41–4.
- Mitzi DB. Polymorphic one-dimensional (N2H4)2ZnTe: soluble precursors for the formation of hexagonal or cubic zinc telluride. Inorganic chemistry. 2005 Oct;44(20):7078–86.
- Knutson JL, Martin JD, Mitzi DB. Tuning the band gap in hybrid tin iodide perovskite semiconductors using structural templating. Inorganic chemistry. 2005 Jun;44(13):4699–705.
- Mitzi DB, Copel M, Chey SJ. Low-voltage transistor employing a high-mobility spin-coated chalcogenide semiconductor. Advanced Materials. 2005 May 13;17(10):1285–9.
- Mitzi DB. Synthesis, structure, and thermal properties of soluble hydrazinium germanium(IV) and tin(IV) selenide salts. Inorganic chemistry. 2005 May;44(10):3755–61.
- Mitzi D, Copel M, Chey SJ. Standing up to be counted. III-Vs Review. 2005 Jan 1;18(6):38–9.
- Mitzi DB. Solution-processed inorganic semiconductors. Journal of Materials Chemistry. 2004 Aug 7;14(15):2355–65.
- Mitzi DB, Kosbar LL, Murray CE, Copel M, Afzali A. High-mobility ultrathin semiconducting films prepared by spin coating. Nature. 2004 Mar;428(6980):299–303.
- Xu Z, Mitzi DB. [CH(3)(CH(2))(11)NH(3)]SnI(3): a hybrid semiconductor with MoO(3)-type tin(II) iodide layers. Inorganic chemistry. 2003 Oct;42(21):6589–91.
- Maxcy KR, Willett RD, Mitzi DB, Afzali A. Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotri- plumbate(II). Acta Crystallographica Section E: Structure Reports Online. 2003 Jun 1;59(6).
- Xu Z, Mitzi DB, Dimitrakopoulos CD, Maxcy KR. Semiconducting perovskites (2-XC6H4C2H4NH3)2SnI4 (X = F, Cl, Br): steric interaction between the organic and inorganic layers. Inorganic chemistry. 2003 Mar;42(6):2031–9.
- Xu ZT, Mitzi D, Dimitrakopoulos CD. Crystal and electronic structure correlation in organic-inorganic perovskites. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2003. p. U87–U87.
- Xu ZT, Mitzi D. New structural motifs in semiconducting organic-inorganic perovskites. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2003. p. U94–U94.
- Xu Z, Mitzi DB, Medeiros DR. [(CH3)3NCH2CH2NH3]SnI4: a layered perovskite with quaternary/primary ammonium dications and short interlayer iodine-iodine contacts. Inorganic chemistry. 2003 Mar;42(5):1400–2.
- Mitzi DB, Xu ZT, Dimitrakopoulos CD, Medeiros DR. Structures, properties and devices based on hybrid perovskites and related materials. In: ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. AMER CHEMICAL SOC; 2003. p. U85–U85.
- Lee Y, Mitzi DB, Barnes PW, Vogt T. Pressure-induced phase transitions and templating effect in three-dimensional organic-inorganic hybrid perovskites. Physical Review B - Condensed Matter and Materials Physics. 2003 Jan 1;68(2).
- Xu ZT, Mitzi DB. SnI42--based hybrid perovskites templated by multiple organic cations:: Combining organic functionalities through noncovalent interactions. CHEMISTRY OF MATERIALS. 2003;15(19):3632–7.
- Mitzi DB, Dimitrakopoulos CD, Rosner J, Medeiros DR, Xu Z, Noyan C. Hybrid field-effect transistor based on a low-temperature melt-processed channel layer. Advanced Materials. 2002 Dec 3;14(23):1772–6.
- Mitzi DB, Medeiros DR, DeHaven PW. Low-temperature melt processing of organic-inorganic hybrid films. Chemistry of Materials. 2002 Jul 27;14(7):2839–41.
- Mitzi DB, Medeiros DR, Dimitrakopoulos CD, Malenfant PRL, Kosbar LL, Xu ZT, et al. Organic-inorganic perovskite semiconductors: Chemistry, properties, and device applications. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2002 Apr 7;223:C23–C23.
- Maxey KR, Mitzi DB, Afzali A, Willett R. Benzylammonium TiN(II) iodide based perovskites. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2002 Apr 7;223:U656–U656.
- Maxcy KR, Mitzi DB, Afzali A, Willett RD. Benzylammonium tin(II) iodide based perovskites. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2002 Apr 7;223:A13–A13.
- Kagan CR, Afzali A, Breen TL, Mitzi DB, Dimitrakopoulos CD, Kosbar LL. Solution deposition and patterning of organic and organic-inorganic thin film transistors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2002 Apr 7;223:D73–D73.
- Mitzi DB, Medeiros DR, Malenfant PRL. Intercalated organic-inorganic perovskites stabilized by fluoroaryl-aryl interactions. Inorganic chemistry. 2002 Apr;41(8):2134–45.
- Mitzi DB. Templating and structural engineering in organic-inorganic perovskites. Journal of the Chemical Society, Dalton Transactions. 2001 Dec 1;(1):1–12.
- Mitzi DB, Dimitrakopoulos CD, Kosbar LL. Structurally tailored organic-inorganic perovskites: Optical properties and solution-processed channel materials for thin-film transistors. Chemistry of Materials. 2001 Nov 9;13(10):3728–40.
- Mitzi DB. Thin-film deposition of organic-inorganic hybrid materials. Chemistry of Materials. 2001 Nov 7;13(10):3283–98.
- Kagan CR, Mitzi DB, Dimitrakopoulos CD, Breen TL, Afzali A, Kosbar LL. Organic-inorganic thin-film field effect transistors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2001 Apr 1;221:U632–U632.
- Mitzi DB, Brock P. Structure and optical properties of several organic-inorganic hybrids containing corner-sharing chains of bismuth iodide octahedra. Inorganic chemistry. 2001 Apr;40(9):2096–104.
- Kagan CR, Mitzi DB, Dimitrakopoulos CD, Breen TL, Afzali A, Kosbar LL. Organic-inorganic perovskites as semiconducting channels in thin film transistors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2001 Apr 1;221:U735–U735.
- Maxcy KR, Willett R, Afzali A, Mitzi DB. Thioxanthene lead perovskite structure and optical properties. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2001 Apr 1;221:U657–U657.
- Mitzi DB, Chondroudis K, Kagan CR. Organic-inorganic electronics. IBM J Res Dev. 2001;45:29–46.
- Mitzi DB, Dimitrakopoulos CD, Kosbar LL. Organic-inorganic electronic devices based on hybrid perovskites. Annual Device Research Conference Digest. 2001 Jan 1;185–6.
- Mitzi DB, Chondroudis K. Crystal structure and properties of dye-containing organic- inorganic perovskites. In: Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals. 2001. p. 549–58.
- Mitzi DB. Organic-inorganic perovskites containing trivalent metal halide layers: the templating influence of the organic cation layer. Inorganic chemistry. 2000 Dec;39(26):6107–13.
- Maxcy KR, Afzali A, Mitzi DB. Crystal growth of perovskites and chain compounds with complex organic cations. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2000 Mar 26;219:U861–U861.
- Chondroudis K, Mitzi DB. The use of ionic salt dyes as amorphous, thermally stable emitting layers in organic light-emitting diodes. Applied Physics Letters. 2000 Jan 3;76(1):58–60.
- Chondroudis K, Mitzi DB, Brock P. Effect of thermal annealing on the optical and morphological properties of (AETH)PbX
4 (X = Br, I) perovskite films prepared using single source thermal ablation. Chemistry of Materials. 2000 Jan 1;12(1):169–75. - Mitzi DB, Chondroudis K, Kagan CR. Design, Structure, and Optical Properties of Organic-Inorganic Perovskites Containing an Oligothiophene Chromophore. Inorganic chemistry. 1999 Dec;38(26):6246–56.
- Kagan CR, Mitzi DB, Dimitrakopoulos CD. Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science (New York, NY). 1999 Oct;286(5441):945–7.
- Mitzi DB. A layered solution crystal growth technique and the crystal structure of (C
6 H5 C2 H4 NH3 )2 PbCl4 . Journal of Solid State Chemistry. 1999 Jan 1;145(2):694–704. - Chondroudis K, Mitzi DB. Electroluminescence from an organic-inorganic perovskite incorporating a quaterthiophene dye within lead halide perovskite layers. Chemistry of Materials. 1999 Jan 1;11(11):3028–30.
- Mitzi DB. A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3) 2PbCl4. Journal of Solid State Chemistry. 1999;145(2):694–704.
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- Mitzi DB, Prikas MT, Chondroudis K. Thin film deposition of organic-inorganic hybrid materials using a single source thermal ablation technique. Chemistry of Materials. 1999 Jan 1;11(3):542–4.
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- Mitzi DB, Liang KN, Wang SM. Synthesis and characterization of [NH2C(I)=NH2]2ASnI5 with A = iodoformamidinium or formamidinium:: The chemistry of cyanamide and tin(II) iodide in concentrated aqueous hydriodic acid solutions. INORGANIC CHEMISTRY. 1998;37(2):321–7.
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2 Sr2 CaCu2 O8+δ to magnetic fields. Physical Review Letters. 1998 Jan 1;80(3):592–5. - Mitzi DB, Liang K. Synthesis, Resistivity, and Thermal Properties of the Cubic Perovskite NH
2 CH=NH2 SnI3 and Related Systems. Journal of Solid State Chemistry. 1997 Dec 1;134(2):376–81. - Mitzi DB, Liang KN. Preparation and properties of(C4H9NH3)2EUI4:: A luminescent organic-inorganic perovskite with a divalent rare-earth metal halide framework. CHEMISTRY OF MATERIALS. 1997;9(12):2990–5.
- Mitzi DB, Liang K. Preparation and Properties of (C4H9NH3)2EuI4: A Luminescent Organic-Inorganic Perovskite with a Divalent Rare-Earth Metal Halide Framework. Chemistry of Materials. 1997;9(12):2990–5.
- Koutselas IB, Mitzi DB, Papavassiliou GC, Papaioannou GJ, Krautscheid H. Optical and related properties and natural one-dimensional semiconductors based on PbI and SnI units. Synthetic Metals. 1997 Jan 1;86(1–3 pt 3):2171–2.
- Wang SM, Mitzi DB, Landrum GA, Genin H, Hoffmann R. Synthesis and solid state chemistry of CH3BiI2: A structure with an extended one-dimensional organometallic framework. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1997;119(4):724–32.
- Mitzi DB, Wang SM. Layered group IVB metal halide organic-inorganic perovskites. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 1996 Mar 24;211:86-INOR.
- Chen BH, Walker D, Scott BA, Mitzi DB. Synthesis and structure of a new perovskite, SrCuO
2.5 . Journal of Solid State Chemistry. 1996 Feb 1;121(2):498–501. - Mitzi DB. Synthesis, crystal structure, and optical and thermal properties of (C4H9NH3)(2)MI(4) (M=Ge, Sn, Pb). CHEMISTRY OF MATERIALS. 1996;8(3):791–800.
- Mitzi DB. Synthesis and Crystal Structure of the Alkylbismuth Diiodides: A Family of Extended One-Dimensional Organometallic Compounds. Inorganic Chemistry. 1996 Jan 1;35(26):7614–9.
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- Mitzi DB, Feild CA, Schlesinger Z, Laibowitz RB. Transport, optical, and magnetic properties of the conducting halide perovskite ch
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2 C(I)=NH2 ]3 MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single (110) Perovskite Sheets. Journal of the American Chemical Society. 1995 Jan 1;117(19):5297–302. - Scott BA, Suard EY, Tsuei CC, Mitzi DB, McGuire TR, Chen BH, et al. Layer dependence of the superconducting transition temperature of HgBa
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- Takigawa M, Mitzi DB. NMR studies of spin dynamics in cuprates. In: Journal of Low Temperature Physics. 1994. p. 89–93.
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- Renner C, Fischer, Kent AD, Mitzi DB, Kapitulnik A. Spatially resolved vacuum tunneling spectroscopy on Bi
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- Hallen HD, Hess HF, Chang AM, Pfeiffer LN, West KW, Mitzi DB. High-resolution scanning hall probe microscopy. In: Proceedings of SPIE - The International Society for Optical Engineering. 1993. p. 152–7.
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- Lombardo LW, Mitzi DB, Kapitulnik A, Leone A. Defect dependence of the irreversibility line in Bi2Sr2CaCu2O8 single crystals. Physical review B, Condensed matter. 1992 Sep;46(9):5615–20.
- Safar H, Gammel PL, Bishop DJ, Mitzi DB, Kapitulnik A. SQUID picovoltometry of single crystal Bi2Sr2CaCu2O8+ delta : Observation of the crossover from high-temperature Arrhenius to low-temperature vortex-glass behavior. Physical review letters. 1992 Apr;68(17):2672–5.
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- Tsuei CC, Chi CC, Frey T, Mitzi DB, Kazyaka T, Haugan T, et al. A jelly-roll process for high temperature superconducting tapes and wires. Materials Chemistry and Physics. 1992 Jan 1;32(1):95–8.
- Yazyi J, Arribére A, Durán C, de la Cruz F, Mitzi DB, Kapitulnik A. Inter- and intraplane softening of the vortex structure in Bi
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- Walstedt RE, Bell RF, Mitzi DB. Nuclear relaxation behavior of the superconducting cuprates: Bi2Sr2CaCu2O8. Physical review B, Condensed matter. 1991 Oct;44(14):7760–3.
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- Hsu JW, Mitzi DB, Kapitulnik A, Lee M. In-plane dissipation maxima and vortex-line distortions in the resistive transitions of oxygen-doped Bi2Sr2CaCu2O8+ delta single crystals. Physical review letters. 1991 Oct;67(15):2095–8.
- Chan LP, Harshman DR, Lynn KG, Massidda S, Mitzi DB. Pair momentum distribution in Bi2Sr2CaCu2O8+ delta measured by positron annihilation: Existence and nature of the Fermi surface. Physical review letters. 1991 Sep;67(10):1350–3.
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