2D Carbides and Nitrides of Transition Metals (MXenes): Synthesis, Structure and Energy Storage Applications
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Wednesday, August 26, 2015 - 12:00pm to 1:00pm
Dr. Yury Gogotsi, Department of Materials Science and Engineering, and A. J. Drexel Nanomaterials Institute, Drexel University
Two-dimensional (2D) solids – the thinnest materials available to us – offer unique properties and a potential path to device miniaturization. The most famous example is graphene, which is an atomically thin layer of carbon atoms bonded together in-plane with sp2 bonds. Recently, an entirely new family of 2D solids – transition metal carbides (Ti2C, Ti3C2, Nb4C3, etc.) and carbonitrides – was discovered by Drexel University scientists [1,2]. Selective etching of the A-group element from a MAX phase results in formation of 2D Mn+1Xn solids, labeled “MXene”. 17 different carbides and carbonitrides have been produced to date [2-5]. Structure and properties of numerous MXenes have been predicted by the density functional theory, showing that MXenes can be metallic or semiconducting (up to 2 eV band gap), depending on their surface termination. Their elastic constants along the basal plane are expected to be higher than that of the binary carbides. Oxygen or OH terminated MXenes, are hydrophilic, but electrically conductive. Hydrazine, urea and other polar organic molecules can intercalate MXenes leading to an increase of the c lattice parameter of MXenes. When dimethyl sulfoxide was intercalated into Ti3C2,followed by sonication in water, a stable colloidal solution of single- and few-layer flakes was produced. One of the many potential applications for 2D Ti3C2 is in electrical energy storage devices, such as batteries, Li-ion capacitors and supercapacitors [3-5]. Cations ranging from Na+ to Mg2+ and Al3+ intercalate MXenes. Ti3C2 paper electrodes, produced by vacuum assisted filtration of an aqueous dispersion of delaminated Ti3C2, show a higher capacity than graphite anodes and also can be charged/discharged at significantly higher rates. They also demonstrate very high intercalation capacitance (up to 900 F/cm3) in aqueous electrolytes .
- 1. M. Naguib, et al, Advanced Materials, 23 (37), 4207-4331 (2011)
- 2. M. Naguib, et al, ACS Nano 6 (2) 1322–1331 (2012)
- 3. O. Mashtalir, et al, Nature Communication, 4, 1716 (2013)
- 4. M. M. Ghidiu, Nature, 516, 78–81 (2014)
- 5. M. Naguib, Y. Gogotsi, Accounts of Chemical Research, 48 (1), 128-135 (2015)
Yury Gogotsi is Distinguished University Professor and Trustee Chair of Materials Science and Engineering at Drexel University. He is the founding Director of the A.J. Drexel Nanomaterials Institute and Associate Editor of ACS Nano. He works on nanostructured carbons and two-dimensional carbides for energy related and biomedical applications. His work on selective extraction synthesis of carbon and carbide nanomaterials with tunable structure and porosity had a strong impact on the field of capacitive energy storage. He has co-authored 2 books, more than 400 journal papers and obtained more than 50 patents. He has received numerous national and international awards for his research. He was recognized as Highly Cited Researcher by Thomson-Reuters in 2014 and elected a Fellow of AAAS, MRS, ECS and ACerS and a member of the World Academy of Ceramics.